Research Output

Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators

  The rapid uptake of energy harvesting triboelectric nanogenerators (TENGs) for self-powered electronics requires the development of high-performance tribo-materials capable of providing large power outputs. This work reports on the synthesis and use of aniline formaldehyde resin (AFR) for energy-harvesting applications. The facile, acidic-medium reaction between aniline and formaldehyde produces the aniline-formaldehyde condensate, which upon an in-vacuo high temperature curing step provides smooth AFR films with abundant nitrogen and oxygen surface functional groups which can acquire a tribo-positive charge and thus endow AFR with a significantly higher positive tribo-polarity than the existing state-of-art polyamide-6 (PA6). A TENG comprising of optimized thin-layered AFR against a polytetrafluoroethylene (PTFE) film produced a peak-to-peak voltage of up to ~1,000 V, a current density of ~65 mA m⁻², a transferred charge density of ~200 μC m⁻² and an instantaneous power output (energy pulse) of ~11 W m⁻² (28.1 μJ cycle⁻¹), respectively. The suitability of AFR was further supported through the Kelvin probe force microscopy (KPFM) measurements, which reveal a significantly higher average surface potential value of 1.147 V for AFR as compared to 0.87 V for PA6 and a step-by-step increase of the surface potential with the increase of energy generation cycles. The work not only proposes a novel and scalable mouldable AFR synthesis process but also expands with excellent prospects, the current portfolio of tribo-positive materials for triboelectric energy harvesting applications.

  • Type:

    Article

  • Date:

    14 November 2019

  • Publication Status:

    Published

  • DOI:

    10.1016/j.nanoen.2019.104291

  • ISSN:

    2211-2855

  • Library of Congress:

    TK Electrical engineering. Electronics Nuclear engineering

  • Dewey Decimal Classification:

    621.3 Electrical & electronic engineering

  • Funders:

    Edinburgh Napier Funded

Citation

Zhao, P., Soin, N., Kumar, A., Shi, L., Guan, S., Tsonos, C., …Luo, J. (2020). Expanding the portfolio of tribo-positive materials: aniline formaldehyde condensates for high charge density triboelectric nanogenerators. Nano Energy, 67, https://doi.org/10.1016/j.nanoen.2019.104291

Authors

Keywords

Aniline formaldehyde resins; tribo-positive polymers; triboelectric nanogenerators; surface potential; KPFM

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